• intermolecular forces are all the different interactions between two molecules or atoms which do not bond together

Coulomb’s force

  • it describes the interaction between two particles based on their charge
  • opposite charges are attracted towards one another, same charges are repelled from one another
  • same charges do not interact via Coulomb’s force
  • Coulomb’s forces can be also described as ion-ion interactions

Van der Waals forces

London dispersion forces

  • it descrbies the interaction of two molecules that do not have a dipole
  • they are the results of temporary dipoles
  • instantaneous dipole occurs when in a non-polar molecule electron density is higher closer to one of the bonding partners
    • this is caused by the constant movement of electrons
    • in the moment instantaneous dipole occurs, the molecule is very slightly polar
  • instantaneous dipoles can cause the induction of dipoles in other molecules surrounding it, thus creating induced dipoles
  • London dispersion forces are therfore instantaneous dipole-induced dipole interactions
  • the strength of these interactions rises with the propability of creating an instantaneous dipole, which rises with the number of electrons
  • they can be found between all molecules and atoms

Debye forces

  • it describes the interaction of two molecules, one which does not have a dipole and one which does
  • permanent dipole exists in all polar molecules
  • permanent dipoles can induce dipoles in other non-polar molecules
  • Debye forces are therore permanent dipole-induced dipole interactions
  • Debye forces occure for example between a molecule of water and an oxygen molecule
    • fish can breath under water thanks to this

Keesom interactions

  • it descries the interaction of two molecules that both have a dipole
  • they are therefore permanent dipole-permanent dipole interactions

Hydrogen bond

  • it is a special case of the Keesom interactions
  • it forms between a hydrogen of a polar compound and the negatively chrged end of another pole molecule
  • it strongly influences the physical properties of different substances

Ion-dipole interaction

  • ions can interact with permanent dipoles rather easily
  • it occurs in solutions, where a polar solvent interacts strongly with ions of salts
    • it results in disolution of the salt, as the molecule is ripped appart